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Metal Doped Core–Shell Metal‐Organic Frameworks@Covalent Organic Frameworks (MOFs@COFs) Hybrids as a Novel Photocatalytic Platform
Author(s) -
Sun Dengrong,
Jang Seungwook,
Yim SeJun,
Ye Lin,
Kim DongPyo
Publication year - 2018
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201707110
Subject(s) - photocatalysis , materials science , microreactor , metal organic framework , dehydrogenation , nanotechnology , tandem , covalent bond , doping , metal , chemical engineering , catalysis , organic chemistry , chemistry , composite material , optoelectronics , adsorption , metallurgy , engineering
Metal doped core–shell Metal‐Organic Frameworks@Covalent Organic Frameworks (MOFs@COFs) are presented as a novel platform for photocatalysis. A palladium (Pd) doped MOFs@COFs in the form of Pd/TiATA@LZU1 shows excellent photocatalytic performance for tandem dehydrogenation and hydrogenation reactions in a continuous‐flow microreactor and a batch system, indicating the great potential of the metal doped MOFs@COFs as a multifunctional platform for photocatalysis. Explanations for the performance enhancement are elucidated. An integrated dual‐chamber microreactor coupled with the metal doped MOFs@COFs is introduced to demonstrate a concept of an intensified green photochemical process, which can be broadly extended to challenging liquid–gas tandem and cascade reactions.