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Holey 2D Nanosheets of Low‐Valent Manganese Oxides with an Excellent Oxygen Catalytic Activity and a High Functionality as a Catalyst for Li–O 2 Batteries
Author(s) -
Adpakpang Kanyaporn,
Oh Seung Mi,
Agyeman Daniel Adjei,
Jin Xiaoyan,
Jarulertwathautpaphat,
Kim In Young,
Sarakonsri Thapanee,
Kang YongMook,
Hwang SeongJu
Publication year - 2018
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201707106
Subject(s) - nanosheet , materials science , overpotential , electrocatalyst , catalysis , chemical engineering , manganese , crystallite , oxygen evolution , calcination , transition metal , nanotechnology , birnessite , oxide , inorganic chemistry , manganese oxide , electrode , electrochemistry , metallurgy , chemistry , biochemistry , engineering
Holey 2D nanosheets of low‐valent Mn 2 O 3 can be synthesized by thermally induced phase transition of exfoliated layered MnO 2 nanosheets. The heat treatment of layered MnO 2 nanosheets at elevated temperatures leads not only to transitions to low‐valent manganese oxides but also to the creation of surface hole in the 2D nanosheet crystallites. Despite distinct phase transitions, highly anisotropic 2D morphology of the precursor MnO 2 material remains intact upon the heat treatment whereas the diameter of surface hole becomes larger with increasing heating temperature. The obtained holey 2D Mn 2 O 3 nanosheets show promising electrocatalyst performances for oxygen evolution reaction, which are much superior to that of nonporous Mn 2 O 3 crystal. Among the present materials, the holey Mn 2 O 3 nanosheet calcined at 500 °C displays the best electrocatalyst functionality with markedly decreased overpotential, indicating the importance of heating condition in optimizing the electrocatalytic activity. Of prime importance is that this material shows much better catalytic activity for Li–O 2 batteries than does nonporous Mn 2 O 3 , underscoring the critical role of porous 2D morphology in this functionality. This study clearly demonstrates the unique advantage of holey 2D nanosheet morphology in exploring economically feasible transition metal oxide‐based electrocatalysts and electrodes for Li–O 2 batteries.