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Orthorhombic Ti 2 O 3 : A Polymorph‐Dependent Narrow‐Bandgap Ferromagnetic Oxide
Author(s) -
Li Yangyang,
Weng Yakui,
Yin Xinmao,
Yu Xiaojiang,
Kumar S. R. Sarath,
Wehbe Nimer,
Wu Haijun,
Alshareef Husam N.,
Pennycook Stephen J.,
Breese Mark B. H.,
Chen Jingsheng,
Dong Shuai,
Wu Tom
Publication year - 2018
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201705657
Subject(s) - materials science , orthorhombic crystal system , ferromagnetism , antiferromagnetism , spintronics , condensed matter physics , band gap , magnetic semiconductor , ground state , magnetism , crystallography , crystal structure , optoelectronics , chemistry , atomic physics , physics
Magnetic semiconductors are highly sought in spintronics, which allow not only the control of charge carriers like in traditional electronics, but also the control of spin states. However, almost all known magnetic semiconductors are featured with bandgaps larger than 1 eV, which limits their applications in long‐wavelength regimes. In this work, the discovery of orthorhombic‐structured Ti 2 O 3 films is reported as a unique narrow‐bandgap (≈0.1 eV) ferromagnetic oxide semiconductor. In contrast, the well‐known corundum‐structured Ti 2 O 3 polymorph has an antiferromagnetic ground state. This comprehensive study on epitaxial Ti 2 O 3 thin films reveals strong correlations between structure, electrical, and magnetic properties. The new orthorhombic Ti 2 O 3 polymorph is found to be n‐type with a very high electron concentration, while the bulk‐type trigonal‐structured Ti 2 O 3 is p‐type. More interestingly, in contrast to the antiferromagnetic ground state of trigonal bulk Ti 2 O 3 , unexpected ferromagnetism with a transition temperature well above room temperature is observed in the orthorhombic Ti 2 O 3 , which is confirmed by X‐ray magnetic circular dichroism measurements. Using first‐principles calculations, the ferromagnetism is attributed to a particular type of oxygen vacancies in the orthorhombic Ti 2 O 3 . The room‐temperature ferromagnetism observed in orthorhombic‐structured Ti 2 O 3 , demonstrates a new route toward controlling magnetism in epitaxial oxide films through selective stabilization of polymorph phases.