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Simultaneously Achieved High Open‐Circuit Voltage and Efficient Charge Generation by Fine‐Tuning Charge‐Transfer Driving Force in Nonfullerene Polymer Solar Cells
Author(s) -
Tang Ailing,
Xiao Bo,
Wang Yuming,
Gao Feng,
Tajima Keisuke,
Bin Haijun,
Zhang ZhiGuo,
Li Yongfang,
Wei Zhixiang,
Zhou Erjun
Publication year - 2018
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201704507
Subject(s) - homo/lumo , organic solar cell , benzotriazole , materials science , open circuit voltage , energy conversion efficiency , charge (physics) , voltage , small molecule , optoelectronics , polymer , molecule , chemistry , physics , organic chemistry , biochemistry , quantum mechanics , metallurgy , composite material
To maximize the short‐circuit current density ( J SC ) and the open circuit voltage ( V OC ) simultaneously is a highly important but challenging issue in organic solar cells (OSCs). In this study, a benzotriazole‐based p‐type polymer (J61) and three benzotriazole‐based nonfullerene small molecule acceptors (BTA1‐3) are chosen to investigate the energetic driving force for the efficient charge transfer. The lowest unoccupied molecular orbital (LUMO) energy levels of small molecule acceptors can be fine‐tuned by modifying the end‐capping units, leading to high V OC (1.15–1.30 V) of OSCs. Particularly, the LUMO energy level of BTA3 satisfies the criteria for efficient charge generation, which results in a high V OC of 1.15 V, nearly 65% external quantum efficiency, and a high power conversion efficiency (PCE) of 8.25%. This is one of the highest V OC in the high‐performance OSCs reported to date. The results imply that it is promising to achieve both high J SC and V OC to realize high PCE with the carefully designed nonfullerene acceptors.