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Spatially Separated CdS Shells Exposed with Reduction Surfaces for Enhancing Photocatalytic Hydrogen Evolution
Author(s) -
Xing Mingyang,
Qiu Bocheng,
Du Mengmeng,
Zhu Qiaohong,
Wang Lingzhi,
Zhang Jinlong
Publication year - 2017
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201702624
Subject(s) - photocatalysis , materials science , rhodamine b , catalysis , chemical engineering , photochemistry , noble metal , irradiation , hydrogen , metal , nanoparticle , nanotechnology , chemistry , metallurgy , biochemistry , physics , organic chemistry , nuclear physics , engineering
To the photocatalytic H 2 evolution, the exposure of a reduction surface over a catalyst plays an important role for the reduction of hydrogen protons. Here, this study demonstrates the design of a noble‐metal‐free spatially separated photocatalytic system exposed with reduction surfaces (MnO x @CdS/CoP) for highly solar‐light‐driven H 2 evolution activity. CoP and MnO x nanoparticles are employed as the electron and hole collectors, which are selectively anchored on the outer and inner surface of CdS shells, respectively. Under solar light irradiation, the photogenerated holes and electrons can directionally move to the MnO x and CoP, respectively, leading to the exposure of a reduction surface. As a result, the H 2 evolution increases from 32.0 to 238.4 µmol h −1 , which is even higher than the activity of platinum‐loaded photocatalyst (MnO x @CdS/Pt). Compared to the pure CdS with serious photocorrosion, the MnO x @CdS/CoP maintains a changeless activity for the H 2 evolution and rhodamine B degradation, even after four cycles. The research provides a new strategy for the preparation of spatially separated photocatalysts with a selective reduction surface.