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3D Self‐Supported Fe‐Doped Ni 2 P Nanosheet Arrays as Bifunctional Catalysts for Overall Water Splitting
Author(s) -
Li Yingjie,
Zhang Haichuan,
Jiang Ming,
Zhang Qian,
He Peilei,
Sun Xiaoming
Publication year - 2017
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201702513
Subject(s) - overpotential , nanosheet , bifunctional , materials science , oxygen evolution , water splitting , chemical engineering , anode , alkaline water electrolysis , cathode , catalysis , electrode , electrolysis , nanotechnology , inorganic chemistry , electrochemistry , chemistry , electrolyte , organic chemistry , photocatalysis , engineering
The development of highly efficient bifunctional electrocatalysts for both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) is crucial for improving the efficiency of overall water splitting, but still remains challenging issue. Herein, 3D self‐supported Fe‐doped Ni 2 P nanosheet arrays are synthesized on Ni foam by hydrothermal method followed by in situ phosphorization, which serve as bifunctional electrocatalysts for overall water splitting. The as‐synthesized (Ni 0.33 Fe 0.67 ) 2 P with moderate Fe doping shows an outstanding OER performance, which only requires an overpotential of ≈230 mV to reach 50 mA cm −2 and is more efficient than the other Fe incorporated Ni 2 P electrodes. In addition, the (Ni 0.33 Fe 0.67 ) 2 P exhibits excellent activity toward HER with a small overpotential of ≈214 mV to reach 50 mA cm −2 . Furthermore, an alkaline electrolyzer is measured using (Ni 0.33 Fe 0.67 ) 2 P electrodes as cathode and anode, respectively, which requires cell voltage of 1.49 V to reach 10 mA cm −2 as well as shows excellent stability with good nanoarray construction. Such good performance is attributed to the high intrinsic activity and superaerophobic surface property.