Premium
A Mesocrystal‐Like Morphology Formed by Classical Polymer‐Mediated Crystal Growth
Author(s) -
Smeets Paul J. M.,
Cho Kang Rae,
Sommerdijk Nico A. J. M.,
De Yoreo James J.
Publication year - 2017
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201701658
Subject(s) - materials science , microscale chemistry , calcite , calcium carbonate , crystal growth , morphology (biology) , crystal (programming language) , particle (ecology) , nanoparticle , nanotechnology , polymer , biomineralization , chemical physics , crystallography , impurity , chemical engineering , mineralogy , composite material , chemistry , computer science , organic chemistry , mathematics education , mathematics , oceanography , engineering , biology , programming language , genetics , geology
Growth by oriented assembly of nanoparticles is a widely reported phenomenon for many crystal systems. While often deduced through morphological analyses, direct evidence for this assembly behavior is limited and, in the calcium carbonate (CaCO 3 ) system, has recently been disputed. However, in the absence of a particle‐based pathway, the mechanism responsible for the creation of the striking morphologies that appear to consist of subparticles is unclear. Therefore, in situ atomic force microscopy is used to investigate the growth of calcite crystals in solutions containing a polymer additive known for its ability to generate crystal morphologies associated with mesocrystal formation. It is shown that classical growth processes that begin with impurity pinning of atomic steps, leading to stabilization of new step directions, creation of pseudo‐facets, and extreme surface roughening, can produce a microscale morphology previously attributed to nonclassical processes of crystal growth by particle assembly.