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Enhanced Capacitive Energy Storage in Polyoxometalate‐Doped Polypyrrole
Author(s) -
Herrmann Sven,
Aydemir Nihan,
Nägele Florian,
Fantauzzi Donato,
Jacob Timo,
TravasSejdic Jadranka,
Streb Carsten
Publication year - 2017
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201700881
Subject(s) - materials science , polypyrrole , supercapacitor , electrochemistry , polymerization , conductive polymer , polyoxometalate , chemical engineering , cationic polymerization , energy storage , capacitance , polymer , nanotechnology , electrode , polymer chemistry , composite material , chemistry , organic chemistry , power (physics) , catalysis , quantum mechanics , physics , engineering
High‐performance batteries and supercapacitors require the molecular‐level linkage of charge transport components and charge storage components. This study shows how redox‐tunable Lindqvist‐type molecular metal oxide anions [V n M 6– n O 19 ] (2+ n )− ( M = W(VI) or Mo(VI); n = 0, 1, 2) can be incorporated in cationic polypyrrole (PPy) conductive polymer films by means of electrochemical polymerization. Electron microscopy and (spectro‐)electrochemistry show that the electroactivity and morphology of the composites can be tuned by Lindqvist anion incorporation. Reductive electrochemical “activation” of the Lindqvist–PPy composites leads to significantly increased electrical capacitance (range: ≈25–38 F g −1 , increase up to ≈25×), highlighting that this general synthetic route gives access to promising capacitive materials with suitable long‐term stability. Electrochemical, electron microscopic, and Raman spectroscopic analyses together with density functional theory (DFT) calculations provide molecular‐level insight into the effects of Lindqvist anion incorporation in PPy films and their role during reductive activation. The study therefore provides fundamental understanding of the principles governing the bottom‐up integration of molecular components into nanostructured composites for electrochemical energy storage.