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Ternary Metal Phosphide with Triple‐Layered Structure as a Low‐Cost and Efficient Electrocatalyst for Bifunctional Water Splitting
Author(s) -
Yu Jing,
Li Qianqian,
Li Yuan,
Xu ChengYan,
Zhen Liang,
Dravid Vinayak P.,
Wu Jinsong
Publication year - 2016
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201603727
Subject(s) - phosphide , materials science , ternary operation , electrocatalyst , water splitting , bifunctional , chemical engineering , oxygen evolution , nickel , nanotechnology , inorganic chemistry , catalysis , electrochemistry , electrode , metallurgy , chemistry , biochemistry , photocatalysis , computer science , engineering , programming language
Development of low‐cost, high‐performance, and bifunctional electrocatalysts for water splitting is essential for renewable and clean energy technologies. Although binary phosphides are inexpensive, their performance is not as good as noble metals. Adding a third metal element to binary phosphides (Ni‐P, Co‐P) provides the opportunity to tune their crystalline and electronic structures and thus their electrocatalytic properties. Here, ternary phosphide (NiCoP) films with different nickel to cobalt ratios via an electrodeposition technique are synthesized. The films have a triple‐layered and hierarchical morphology, consisting of nanosheets in the bottom layer, ≈90–120 nm nanospheres in the middle layer, and larger spherical particles on the top layer. The ternary phosphides exhibit versatile activities that are strongly dependent on the Ni/Co ratios and Ni 0.51 Co 0.49 P film is found to have the best electrocatalytic activities for both hydrogen evolution reactions and oxygen evolution reactions. The high performance of the ternary phosphide film is attributed to enhanced electric conductivity so that reaction kinetics is accelerated, enlarged surface area due to the hierarchical and three‐layered morphology, and increased local electric dipole so that the energy barrier for the water splitting reaction is lowered.