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Metal‐Free Sensitizers Containing Hydantoin Acceptor as High Performance Anchoring Group for Dye‐Sensitized Solar Cells
Author(s) -
Guo FuLing,
Li ZhaoQian,
Liu XuePeng,
Zhou Li,
Kong FanTai,
Chen WangChao,
Dai SongYuan
Publication year - 2016
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201601305
Subject(s) - hydantoin , anchoring , dye sensitized solar cell , materials science , acceptor , photochemistry , electron acceptor , adsorption , photocurrent , organic chemistry , chemistry , electrolyte , optoelectronics , physics , structural engineering , electrode , engineering , condensed matter physics
The anchoring group in dye‐sensitized solar cells (DSSCs) profoundly affects the electron injection and durability on TiO 2 films interface. Here, the hydantoin acceptor is introduced as anchoring group for DSSCs. The hydantoin based sensitizer achieves a photovoltaic efficiency of 7.66%, compared to 4.90% for sensitizer containing the conventional cyanoacrylic acid as anchoring group. Remarkably, the hydantoin anchoring group significantly enhances the electron‐injection efficiency ( Φ inj ) and photocurrent ( J sc ). The time dependent adsorption and desorption data indicate the strong binding strength and the superiority of stability for hydantoin based sensitizers. The Fourier transform infrared measurements investigate the adsorption mechanism of hydantoin on TiO 2 interface. These results strongly corroborate the advantages of incorporating hydantoin as acceptor and anchoring group. As a consequence, the sensitizer HY‐4 with hydantoin approaches the photovoltaic efficiency of 8.32% under 0.1 sunlight illumination. These observations offer a new route to design and develop efficient sensitizers for DSSCs.