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Contactless and Rapid Discrimination of Improvised Explosives Realized by Mn 2+ Doping Tailored ZnS Nanocrystals
Author(s) -
Wu Zhaofeng,
Zhou Chaoyu,
Zu Baiyi,
Li Yushu,
Dou Xincun
Publication year - 2016
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201600592
Subject(s) - materials science , doping , explosive material , nanocrystal , nanotechnology , optoelectronics , chemistry , organic chemistry
In order to sensitively, selectively, and rapidly detect the constituents relevant to improvised explosive devices (IEDs), the sensing properties of ZnS nanocrystals (NCs) are regulated by tailoring the doping level of Mn 2+ . The responses of the sensors fabricated by ZnS NCs with different Mn‐doping levels (Mn:ZnS) toward the constituents, such as sulphur powder and black powder, generally increases first and then decreases with the increase of the concentration of doped Mn 2+ , and reaches the climate with an atomic ratio of 2.23% at room temperature. The sensory array based on eight sensors of Mn:ZnS NCs can realize the detection of two typical military explosives and six constituents relevant to IEDs within 7 s and can recover in 19 s. Furthermore, the fingerprinting of the constituents is achieved by pattern recognizing the inherent kinetics and thermodynamics of interaction between the sensory array and the constituents. Thus, a simple chemiresistive sensing strategy based on semiconductor NCs which can rapidly, supersensitively, and discriminatively detect the constituents relevant to IEDs is explored for the first time.