Premium
Bimetal–Organic Framework: One‐Step Homogenous Formation and its Derived Mesoporous Ternary Metal Oxide Nanorod for High‐Capacity, High‐Rate, and Long‐Cycle‐Life Lithium Storage
Author(s) -
Li Hao,
Liang Ming,
Sun Weiwei,
Wang Yong
Publication year - 2016
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201504312
Subject(s) - nanorod , materials science , mesoporous material , bimetallic strip , bimetal , ternary operation , oxide , lithium (medication) , chemical engineering , metal , nanotechnology , niobium oxide , nanoparticle , catalysis , organic chemistry , composite material , metallurgy , chemistry , medicine , engineering , endocrinology , computer science , programming language
Metal–organic frameworks (MOFs) and relative structures with uniform micro/mesoporous structures have shown important applications in various fields. This paper reports the synthesis of unprecedented mesoporous Ni x Co 3− x O 4 nanorods with tuned composition from the Co/Ni bimetallic MOF precursor. The Co/Ni‐MOFs are prepared by a one‐step facile microwave‐assisted solvothermal method rather than surface metallic cation exchange on the preformed one‐metal MOF template, therefore displaying very uniform distribution of two species and high structural integrity. The obtained mesoporous Ni 0.3 Co 2.7 O 4 nanorod delivers a larger‐than‐theoretical reversible capacity of 1410 mAh g −1 after 200 repetitive cycles at a small current of 100 mA g −1 with an excellent high‐rate capability for lithium‐ion batteries. Large reversible capacities of 812 and 656 mAh g −1 can also be retained after 500 cycles at large currents of 2 and 5 A g −1 , respectively. These outstanding electrochemical performances of the ternary metal oxide have been mainly attributed to its interconnected nanoparticle‐integrated mesoporous nanorod structure and the synergistic effect of two active metal oxide components.