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Structural Origins for Tunable Open‐Circuit Voltage in Ternary‐Blend Organic Solar Cells
Author(s) -
Khlyabich Petr P.,
Rudenko Andrey E.,
Thompson Barry C.,
Loo YuehLin
Publication year - 2015
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201502287
Subject(s) - homo/lumo , ternary operation , materials science , open circuit voltage , organic solar cell , polymer solar cell , acceptor , polymer , chemical physics , chemical engineering , organic chemistry , molecule , composite material , voltage , chemistry , condensed matter physics , physics , quantum mechanics , computer science , engineering , programming language
Ternary‐blend bulk‐heterojunction solar cells have provided a unique opportunity for tuning the open‐circuit voltage ( V oc ) as the “effective” highest occupied molecular orbital (HOMO) or lowest unoccupied molecular orbital (LUMO) energy levels shift with active‐layer composition. Grazing‐incidence X‐ray diffraction (GIXD) measurements performed on such ternary‐blend thin films reveal evidence that the two polymer donors interact intimately; their ionization potentials are thus reflections of the blend compositions. In ternary‐blend thin films in which the two polymer donors do not interact physically, the polymer donors each retain their molecular electronic character; solar cells constructed with these ternary blends thus exhibit V oc s that are pinned to the energy level difference between the highest of the two lying HOMO and the LUMO of the electron acceptor. These observations are consistent with the organic alloy model proposed earlier. Quantification of the square of the square‐root differences of the surface energies of the components provides a proxy for the Flory–Huggins interaction parameter for polymer donor pairs in these ternary‐blend systems. Of the three ternary‐blend systems examined herein, this quantity has to be below 0.094 in order for ternary‐blend solar cells to exhibit tunable V oc .