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Uncovering the Structure of Nafion–SiO 2 Hybrid Ionomer Membranes for Prospective Large‐Scale Energy Storage Devices
Author(s) -
Davis Eric M.,
Kim Jenny,
Oleshko Vladimir P.,
Page Kirt A.,
Soles Christopher L.
Publication year - 2015
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201501116
Subject(s) - nafion , membrane , materials science , vanadium , ionomer , chemical engineering , nanocomposite , nanotechnology , electrochemistry , composite material , copolymer , chemistry , electrode , polymer , engineering , biochemistry , metallurgy
Nafion nanocomposite membranes are attractive candidates for the ion conducting phase in energy storage devices such as vanadium redox flow batteries. Herein, vanadium crossover and Nafion–SiO 2 nanostructure are quantified in a series of hybrid membranes created via solution‐casting Nafion films with discrete SiO 2 nanoparticles, as well as membranes created using an in situ silica sol–gel condensation process. The crossover of vanadium ions is suppressed in all Nafion membranes with the SiO 2 inorganic phase when compared to unannealed, neat Nafion membranes. However, it is also observed that annealing the neat Nafion membranes is equally as effective at suppressing vanadium crossover. Small‐angle neutron scattering measurements show that no significant changes to the Nafion structure occurred in membranes with discrete nanoparticles. In contrast, drastic changes in the scattering profiles of the Nafion–SiO 2 membranes created via sol–gel chemistry are observed, where the SiO 2 nanoclusters are determined to be on the order of 10 nm in diameter. These scattering length scales are verified through real space images using transmission electron microscopy. Insights from this investigation help elucidate the structure of the Nafion–SiO 2 membranes and suggest that the current hypothesis by how vanadium crossover is reduced may not be fully accurate.