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Hematite Films Decorated with Nanostructured Ferric Oxyhydroxide as Photoanodes for Efficient and Stable Photoelectrochemical Water Splitting
Author(s) -
Yu Qing,
Meng Xianguang,
Wang Tao,
Li Peng,
Ye Jinhua
Publication year - 2015
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201500383
Subject(s) - photocurrent , hematite , water splitting , materials science , chemical engineering , ferric , kinetics , cathodic protection , nanotechnology , photocatalysis , anode , catalysis , optoelectronics , electrode , metallurgy , chemistry , physics , quantum mechanics , biochemistry , engineering
Hematite photoanodes are decorated with nanostructured FeOOH by photoelectrodeposition. An obvious cathodic shift in the photocurrent onset potential is observed, while four‐times enhancement of photocurrent density enhancement is acheived with FeOOH present. This can be ascribed to the high reaction area for the structure and high electrocatalytic activity of nanostructured FeOOH, which increases the amount of photogenerated holes involved in the water oxidation reaction and accelerates the kinetics of water oxidation. Furthermore, the obtained Fe 2 O 3 /FeOOH photoanode achieves considerable O 2 evolution rate (10.1 μmol h −1 cm −2 ) under AM 1.5 G illumination and is maintained for as long as 70 h. The Fe 2 O 3 /FeOOH films show visible light response, high photocurrent density, and long‐term stability, and they are well qualified photoanode materials and a promising candidate for photoelectrochemical water splitting.