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Rational Design of Small Molecular Donor for Solution‐Processed Organic Photovoltaics with 8.1% Efficiency and High Fill Factor via Multiple Fluorine Substituents and Thiophene Bridge
Author(s) -
Wang JinLiang,
Yin QingRu,
Miao JingSheng,
Wu Zhuo,
Chang ZhengFeng,
Cao Yue,
Zhang RuBo,
Wang JieYu,
Wu HongBin,
Cao Yong
Publication year - 2015
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201500190
Subject(s) - thiophene , materials science , homo/lumo , energy conversion efficiency , organic solar cell , electron mobility , annealing (glass) , photoactive layer , active layer , molecular orbital , chemical engineering , small molecule , polymer solar cell , molecule , optoelectronics , organic chemistry , nanotechnology , layer (electronics) , polymer , thin film transistor , composite material , chemistry , engineering , biochemistry
A series of tetrafluorine‐substituted small molecules with a D 1 ‐A‐D 2 ‐A‐D 1 linear framework based on indacenodithiophene and difluorobenzothiadiazole is designed and synthesized for application as donor materials in solution‐processed small‐molecule organic solar cells. The impacts of thiophene π‐bridge and multiple fluorinated modules on the photophysical properties, the energy levels of the highest occupied molecular orbitals (HOMO) and lowest unoccupied molecular orbitals (LUMO), charge carrier mobility, the morphologies of blend films, and their photovoltaic properties as electron donor material in the photoactive layer are investigated. By incorporating multiple fluorine substituents of benzothiadiazole and inserting two thiophene spacers, the fill factor ( FF ), open‐circuit voltage, and short‐circuit current density are dramatically improved in comparison with fluorinated‐free materials. With the solvent vapor annealing treatment, further enhancement in charge carrier mobility and power conversion efficiency (PCE) are achieved. Finally, a high PCE of 8.1% with very‐high FF of 0.76 for BIT‐4F‐ T/PC 71 BM is achieved without additional additive, which is among one of the highest reported for small‐molecules‐based solar cells with PCE over 8%. The results reported here clearly indicate that high PCE in solar cells based small molecules can be significantly increased through careful engineering of the molecular structure and optimization on the morphology of blend films by solvent vapor annealing.