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Supramolecular Materials: Investigating Local Structure in Layered Double Hydroxides with 17 O NMR Spectroscopy (Adv. Funct. Mater. 12/2014)
Author(s) -
Zhao Li,
Qi Zhe,
Blanc Frédéric,
Yu Guiyun,
Wang Meng,
Xue Nianhua,
Ke Xiaokang,
Guo Xuefeng,
Ding Weiping,
Grey Clare P.,
Peng Luming
Publication year - 2014
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201470078
Subject(s) - materials science , magic angle spinning , layered double hydroxides , supramolecular chemistry , nuclear magnetic resonance spectroscopy , spectroscopy , spinning , crystallography , nuclear magnetic resonance , inorganic chemistry , crystal structure , polymer chemistry , chemistry , physics , quantum mechanics , hydroxide
17 O magic angle spinning NMR is used by L. Peng and co‐workers to probe the cation ordering and interactions between intralayer cations and interlayer anions in layered double hydroxides via the “memory effect”. In particular, Mg 3 OH and Mg 2 AlOH can be distinguished, and their structures are shown here to the right and left, respectively, of the 3D NMR data.