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Smart Hybridization of TiO 2 Nanorods and Fe 3 O 4 Nanoparticles with Pristine Graphene Nanosheets: Hierarchically Nanoengineered Ternary Heterostructures for High‐Rate Lithium Storage
Author(s) -
Pan Long,
Zhu XiaoDong,
Xie XuMing,
Liu YiTao
Publication year - 2015
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201404348
Subject(s) - materials science , graphene , anode , ternary operation , nanotechnology , heterojunction , nanorod , lithium (medication) , nanoparticle , dopant , context (archaeology) , energy storage , chemical engineering , doping , electrode , optoelectronics , power (physics) , medicine , paleontology , chemistry , physics , quantum mechanics , endocrinology , computer science , engineering , biology , programming language
Today, the ever‐increasing demand for large‐size power tools has provoked worldwide competition in developing lithium‐ion batteries having higher energy and power densities. In this context, advanced anode materials are being extensively pursued, among which TiO 2 is particularly promising owing to its high safety, excellent cost and environmental performances, and high cycle stability. However, TiO 2 is faced with two detrimental deficiencies, that is, extremely low theoretical capacity and conductivity. Herein, a smart hybridization strategy is proposed for the hierarchical co‐assembly of TiO 2 nanorods and Fe 3 O 4 nanoparticles on pristine graphene nanosheets, aiming to simultaneously address the capacity and conductivity deficiencies of TiO 2 by coupling it with high‐capacity (Fe 3 O 4 ) and high‐conductivity (pristine graphene) components. The resulting novel, multifunctional ternary heterostructures effectively integrate the intriguing functionalities of the three building blocks: TiO 2 as the major active material can adequately retain such merits as high safety and cycle stability, Fe 3 O 4 as the auxiliary active material can contribute extraordinarily high capacities, and pristine graphene as the conductive dopant can guarantee sufficient percolation pathways. Benefiting from a remarkable synergy, the ternary heterostructures deliver superior reversible capacities and rate capabilities, thus casting new light on developing next‐generation, high‐performance anode materials.