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Multidimensional Vascularized Polymers using Degradable Sacrificial Templates
Author(s) -
Gergely Ryan C. R.,
Pety Stephen J.,
Krull Brett P.,
Patrick Jason F.,
Doan Thu Q.,
Coppola Anthony M.,
Thakre Piyush R.,
Sottos Nancy R.,
Moore Jeffrey S.,
White Scott R.
Publication year - 2015
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201403670
Subject(s) - materials science , template , thermosetting polymer , polymer , nanotechnology , composite material
Complex multidimensional vascular polymers are created, enabled by sacrificial template materials of 0D to 3D. Sacrificial material consisting of the commodity biopolymer poly(lactic acid) is treated with a tin catalyst to accelerate thermal depolymerization, and formed into sacrificial templates across multiple dimensions and spanning several orders of magnitude in scale: spheres (0D), fibers (1D), sheets (2D), and 3D printed. Templates are embedded in a thermosetting polymer and removed using a thermal treatment process, vaporization of sacrificial components (VaSC), leaving behind an inverse replica. The effectiveness of VaSC is verified both ex situ and in situ, and the resulting structures are validated via flow rate testing. The VaSC platform is expanded to create vascular and porous architectures across a wide range of size and geometry, allowing engineering applications to take advantage of vascular designs optimized by biology.