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Highly Efficient and Robust Blue Phosphorescent Pt(II) Compounds with a Phenyl‐1,2,3‐triazolyl and a Pyridyl‐1,2,4‐triazolyl Chelate Core
Author(s) -
Wang Xiang,
Gong ShaoLong,
Song Datong,
Lu ZhengHong,
Wang Suning
Publication year - 2014
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201402366
Subject(s) - phosphorescence , ligand (biochemistry) , chelation , molecule , materials science , substituent , photochemistry , excimer , fluorescence , chemistry , stereochemistry , organic chemistry , biochemistry , physics , receptor , quantum mechanics , metallurgy
A new class of brightly phosphorescent Pt(II) compounds that contain an N ∧ C‐chelate phenyl‐1,2,3‐triazolyl ligand (ptrz) and an N ∧ C‐chelate pyridyl‐1,2,4‐triazolyl ligand (pytrz) in the central core is achieved. The impact of various substituent groups on phosphorescence of this class of molecules is examined. Crystal structural analyses revealed that this class of compounds has a great tendency to form stacked dimers—one of which is persistent even in the gas phase—leading to excimer emission. The introduction of bulky substituents, such as diphenyl amino (NPh 2 ) or trityl (CPh 3 ), is found to greatly diminish the excimer emission. Using this approach, several highly efficient blue and green phosphorescent Pt(II) compounds with λ em at ≈450–460 nm and Φ p ≈ 0.70 to 1.00 are obtained. These molecules are highly robust with exceptionally high thermal stability. Bright bluish‐green electrophosphorescent devices with external quantum efficiencies as high as 16.7% are fabricated.