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Lanthanide Ion Codoped Emitters for Tailoring Emission Trajectory and Temperature Sensing
Author(s) -
Zhao ShuNa,
Li LeiJiao,
Song XueZhi,
Zhu Min,
Hao ZhaoMin,
Meng Xing,
Wu LanLan,
Feng Jing,
Song ShuYan,
Wang Cheng,
Zhang HongJie
Publication year - 2015
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201402061
Subject(s) - lanthanide , materials science , luminescence , excitation wavelength , ion , fluorescence , metal organic framework , atmospheric temperature range , thermometer , lanthanide contraction , gadolinium , nanotechnology , analytical chemistry (journal) , chemistry , optoelectronics , wavelength , optics , organic chemistry , thermodynamics , adsorption , physics , metallurgy
A series of lanthanide metal‐organic frameworks (Ln‐MOFs) are synthesized through solvothermal conditions with 1,3‐bis(4‐carboxyphenyl)imidazolium (H 2 L). Owing to the lanthanide contraction effect, two different types of Ln‐MOFs, namely, {[Ln(L) 2 (OH)]·3H 2 O} n (Ln:Pr, Nd, Sm) and {[Ln(L) 2 (COO)(H 2 O) 2 ]·H 2 O} n (Ln: Eu, Gd, Tb, Dy, Tm, Yb, Y), and their corresponding codoped Ln‐MOFs Eu x Tb 1‐ x L are obtained. With careful adjustment of the relative concentration of the lanthanide ions and the excitation wavelength, the color of the luminescence can be systematically modulated and white light emission can be further successfully achieved. Furthermore, by virtue of the temperature‐dependent luminescent behavior, Eu 0.2 Tb 0.8 L allows for the design of a thermometer with an excellent linear response to temperature over a wide range, from 40 to 300 K. This work highlights the practical applications of Ln‐MOFs for tailoring fluorescent color and even obtaining practical white light emission, and especially for sensing temperature as luminescent thermometers in a single framework by controlling in different ways.