Premium
Nitrogen‐Doped Carbon Networks for High Energy Density Supercapacitors Derived from Polyaniline Coated Bacterial Cellulose
Author(s) -
Long Conglai,
Qi Dongping,
Wei Tong,
Yan Jun,
Jiang Lili,
Fan Zhuangjun
Publication year - 2014
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201304269
Subject(s) - supercapacitor , materials science , polyaniline , bacterial cellulose , carbonization , capacitance , carbon fibers , chemical engineering , electrode , activated carbon , nanotechnology , cellulose , composite material , polymer , organic chemistry , adsorption , composite number , polymerization , chemistry , scanning electron microscope , engineering
Bacterial cellulose (BC) is used as both template and precursor for the synthesis of nitrogen‐doped carbon networks through the carbonization of polyaniline (PANI) coated BC. The as‐obtained carbon networks can act not only as support for obtaining high capacitance electrode materials such as activated carbon (AC) and carbon/MnO 2 hybrid material, but also as conductive networks to integrate active electrode materials. As a result, the as‐assembled AC//carbon‐MnO 2 asymmetric supercapacitor exhibits a considerably high energy density of 63 Wh kg −1 in 1.0 m Na 2 SO 4 aqueous solution, higher than most reported AC//MnO 2 asymmetric supercapacitors. More importantly, this asymmetric supercapacitor also exhibits an excellent cycling performance with 92% specific capacitance retention after 5000 cycles. Those results offer a low‐cost, eco‐friendly design of electrode materials for high‐performance supercapacitors.