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Combinatorial Atmospheric Pressure Chemical Vapor Deposition of F:TiO 2 ; the Relationship between Photocatalysis and Transparent Conducting Oxide Properties
Author(s) -
Kafizas Andreas,
Noor Nuruzzaman,
Carmichael Penelope,
Scanlon David O.,
Carmalt Claire J.,
Parkin Ivan P.
Publication year - 2014
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201301333
Subject(s) - anatase , materials science , photocatalysis , doping , chemical vapor deposition , brookite , trifluoroacetic acid , atmospheric pressure , titanium dioxide , electrical resistivity and conductivity , titanium tetrachloride , analytical chemistry (journal) , fluorine , titanium , oxide , chemical engineering , nanotechnology , catalysis , organic chemistry , optoelectronics , composite material , chemistry , oceanography , geology , electrical engineering , metallurgy , engineering
Combinatorial atmospheric pressure chemical vapor deposition (APCVD) is used to deposit anatase TiO 2 with a graded level of F‐doping between 1.10 ≤ F:Ti (at%) ≤ 2.57 from the reaction of titanium tetrachloride, ethyl acetate and trifluoroacetic acid at 500 °C on glass. The photocatalytic activity and electrical resistivity of 200 allotted positions across a grid are screened using high‐throughput techniques. A blue region of film is singled out for containing the lowest electrical resistivities of any previously reported doped or undoped TiO 2 ‐based system formed by APCVD (ρ ≈ 0.22–0.45 Ω cm, n = 0.8–1.2 × 10 18 cm −3 , μ = 18–33 cm 2 V −1 s −1 ). The blue region contains a lower fluorine doping level (F:Ti ≈ 1.1–1.6%, E bg ≈ 3.06 eV) than its neighboring colorless region (F:Ti ≈ 2.3–2.6%, E bg ≈ 3.15–3.21 eV, ρ ≈ 0.61–1.3 Ω cm). State‐of‐the‐art hybrid density functional theory calculations were employed to elucidate the nature of the different doping behaviors. Two distinct fluorine doping environments were present. At low concentrations, F substituting for O (F O ) dominates, forming blue F:TiO 2 . At high concentrations, negatively charged fluorine interstitials (F i −1 ) begin to dominate, forming transparent F:TiO 2 .