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A Bottom‐Up Approach to Build 3D Architectures from Nanosheets for Superior Lithium Storage
Author(s) -
Gong Yongji,
Yang Shubin,
Zhan Liang,
Ma Lulu,
Vajtai Robert,
Ajayan Pulickel M.
Publication year - 2014
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201300844
Subject(s) - materials science , graphene , nanotechnology , lithium (medication) , energy storage , oxide , stack (abstract data type) , van der waals force , electrode , molecule , computer science , medicine , power (physics) , chemistry , physics , organic chemistry , quantum mechanics , endocrinology , metallurgy , programming language
Two‐dimensional (2D) atomic layers such as graphene, and metal chalcogenides have recently attracted tremendous attention due to their unique properties and potential applications. Unfortunately, in most cases, the free‐standing nanosheets easily re‐stack due to their van der Waals forces, and lose the advantages of their separated atomic layer state. Here, a bottom‐up approach is developed to build three‐dimensional (3D) architectures by 2D nanosheets such as MoS 2 and graphene oxide nanosheets as building blocks, the thin nature of which can be well retained. After simply chemical reduction, the resulting 3D MoS 2 ‐graphene architectures possess high surface area, porous structure, thin walls and high electrical conductivity. Such unique features are favorable for the rapid diffusions of both lithium ions and electrons during lithium storage. As a consequence, MoS 2 ‐graphene electrodes exhibit high reversible capacity of ≈1200 mAh g −1 , with very good cycling performance. Moreover, such a simple and low‐cost assembly protocol can provide a new pathway for the large‐scale production of various functional 3D architectures for energy storage and conversions.