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Energetics of Donor‐Doping, Metal Vacancies, and Oxygen‐Loss in A‐Site Rare‐Earth‐Doped BaTiO 3
Author(s) -
Freeman Colin L.,
Dawson James A.,
Chen HungRu,
Ben Liubin,
Harding John H.,
Morrison Finlay D.,
Sinclair Derek C.,
West Anthony R.
Publication year - 2013
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201203147
Subject(s) - doping , materials science , ionic bonding , oxygen , metal , ionic conductivity , chemical physics , inorganic chemistry , ion , chemistry , optoelectronics , electrode , metallurgy , organic chemistry , electrolyte
The energetics of La‐doping in BaTiO 3 are reported for both (electronic) donor‐doping with the creation of Ti 3+ cations and ionic doping with the creation of Ti vacancies. The experiments (for samples prepared in air) and simulations demonstrate that ionic doping is the preferred mechanism for all concentrations of La‐doping. The apparent disagreement with electrical conduction of these ionic doped samples is explained by subsequent oxygen‐loss, which leads to the creation of Ti 3+ cations. Simulations show that oxygen‐loss is much more favorable in the ionic‐doped system than undoped BaTiO 3 due to the unique local structure created around the defect site. These findings resolve the so‐called “donor‐doping” anomaly in BaTiO 3 and explain the source of semiconductivity in positive temperature coefficient of resistance (PTCR) BaTiO 3 thermistors.