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Templated Crosslinked Imidazolyl Acrylate for Electronic Detection of Nitroaromatic Explosives
Author(s) -
Kong Hoyoul,
Sinha Jasmine,
Sun Jia,
Katz Howard E.
Publication year - 2013
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201201711
Subject(s) - trinitrotoluene , materials science , conductance , acrylate , resistive touchscreen , explosive material , stacking , polymer , chemical engineering , nanotechnology , photochemistry , organic chemistry , chemistry , copolymer , composite material , mathematics , combinatorics , electrical engineering , engineering
A low‐voltage operable, highly sensitive, and selectively responsive polymer for the detection of nitroaromatic explosives is investigated. Resistive devices are fabricated by simple spin‐coating on flexible and transparent substrates in addition to silicon substrates and are stable under ambient temperature and oxygen levels before exposure to the nitroaromatics. After exposure to 2,4,6‐trinitrotoluene (TNT), the devices show increased conductance, even with picogram (pg) quantities of TNT, accompanied by a confirming color change from colorless to deep red. The relative conductance increase per unit exposure is the highest yet reported for TNT. Aromatic anion salts, on the other hand, do not induce any electronic responses. 1 H NMR and microscopic analyses show chemical interactions and morphological changes correlated with the electronic responses, some of which are specific to TNT in relation to other nitroaromatics. The binding constant for the imidazole rings and TNT is on the order of tens of M −1 . The materials are promising for rapid indication of exposure to nitroaromatic compounds.