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Hybrid Templated Synthesis of Crack‐Free, Organized Mesoporous TiO 2 Electrodes for High Efficiency Solid‐State Dye‐Sensitized Solar Cells
Author(s) -
Park Jung Tae,
Chi Won Seok,
Roh Dong Kyu,
Ahn Sung Hoon,
Kim Jong Hak
Publication year - 2013
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201200823
Subject(s) - materials science , anatase , chemical engineering , dye sensitized solar cell , mesoporous material , thermogravimetric analysis , polymerization , atom transfer radical polymerization , electrolyte , polymer , photocatalysis , electrode , composite material , organic chemistry , chemistry , engineering , catalysis
Organic/inorganic hybrid templates, i.e., aluminium oxide (Al 2 O 3 ) nanoparticles grafted with poly(oxyethylene) methacrylate, Al 2 O 3 ‐POEM, are synthesized via surface‐initiated atom transfer radical polymerization (ATRP), as confirmed by Fourier transform‐infrared spectroscopy (FT‐IR) and thermogravimetric analysis (TGA). Upon combining the Al 2 O 3 ‐POEM with titanium(IV) isopropoxide (TTIP), hydrophilic TTIP is selectively confined in the hydrophilic POEM chains through hydrogen bonding interactions. Following the calcination at 450 °C and the selective etching of Al 2 O 3 with NaOH, the OM‐TiO 2 films with high surface areas, good interconnectivity, and anatase phase are obtained. The solid‐state dye‐sensitized solar cells (ssDSSCs) fabricated with OM‐TiO 2 photoelectrodes and a polymerized ionic liquid (PIL) show a high energy conversion efficiency of 7.3% at 100 mW cm −2 , which is one of the highest values for ssDSSCs. The high cell performance is due to the well‐organized structure, resulting in improved dye loading, excellent pore filling of electrolyte, enhanced light harvesting, and reduced charge recombination.