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Manipulation of the Open‐Circuit Voltage of Organic Solar Cells by Desymmetrization of the Structure of Acceptor–Donor–Acceptor Molecules
Author(s) -
Demeter Dora,
Rousseau Theodulf,
Leriche Philippe,
Cauchy Thomas,
Po Riccardo,
Roncali Jean
Publication year - 2011
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201101508
Subject(s) - acceptor , open circuit voltage , homo/lumo , organic solar cell , electron acceptor , molecule , photochemistry , cyclic voltammetry , chemistry , materials science , crystallography , electrochemistry , organic chemistry , voltage , electrode , physics , quantum mechanics , condensed matter physics , polymer
The synthesis of acceptor–donor–acceptor (A–D–A) molecules based on a septithiophene chain with terminal electron acceptor groups is reported. Using a dicyanovinyl‐ (DCV) substituted molecule as reference, another symmetrical A–D–A donor containing thiobarbituric (TB) groups is synthesized and these two acceptor groups are combined to produce the unsymmetrical A–D–A′ compound. The electronic properties of the donors are analyzed by cyclic voltammetry and UV‐Vis absorption spectroscopy and their photovoltaic properties are characterized on bilayer planar heterojunction cells that include spun‐cast donor films and vacuum‐deposited C 60 as acceptor. Optical and electrochemical data show that replacement of DCV by TB leads to a small increase of the HOMO level and to a larger decrease of the LUMO, which result in a reduced band‐gap. The desymmetrized compound presents the lowest oxidation potential in solution but the highest oxidation onset in the solid state, which leads to a significant increase of the open‐circuit voltage of the resulting solar cells.