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Biomimetic Solid‐Solution Precursors of Metal Carbonate for Nanostructured Metal Oxides: MnO/Co and MnO‐CoO Nanostructures and Their Electrochemical Properties
Author(s) -
Kokubu Takao,
Oaki Yuya,
Hosono Eiji,
Zhou Haoshen,
Imai Hiroaki
Publication year - 2011
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201101138
Subject(s) - materials science , cobalt , manganese , nanocomposite , electrochemistry , metal , anode , chemical engineering , inorganic chemistry , monoxide , electrode , nanotechnology , metallurgy , chemistry , engineering
Biomimetic solid solutions of manganese and cobalt carbonates (MnCO 3 –CoCO 3 ) are used as the precursors for the synthesis of the corresponding metal oxides. The different structures of the metal oxides with porous morphologies, such as pure manganese monoxide (MnO), the solid solution of manganese and cobalt monoxide (MnO–CoO), and the nanocomposite of MnO and metallic cobalt (MnO/Co), are obtained by the appropriate thermal treatments under a reduction atmosphere. The contents of cobalt species can be controlled by the initial cobalt concentration in the MnCO 3 –CoCO 3 precursors. The resultant MnO/Co nanocomposites show the enhanced charge–discharge cycle stability and rate performance as an anode material of lithium‐ion battery.