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Well‐Ordered Large‐Pore Mesoporous Anatase TiO 2 with Remarkably High Thermal Stability and Improved Crystallinity: Preparation, Characterization, and Photocatalytic Performance
Author(s) -
Zhou Wei,
Sun Fanfei,
Pan Kai,
Tian Guohui,
Jiang Baojiang,
Ren Zhiyu,
Tian Chungui,
Fu Honggang
Publication year - 2011
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.201002535
Subject(s) - mesoporous material , materials science , anatase , crystallinity , chemical engineering , photocatalysis , calcination , mesoporous organosilica , x ray photoelectron spectroscopy , raman spectroscopy , specific surface area , thermal stability , mesoporous silica , organic chemistry , composite material , chemistry , catalysis , physics , optics , engineering
Thermally‐stable, ordered mesoporous anatase TiO 2 with large pore size and high crystallinity has been successfully synthesized through an evaporation‐induced self‐assembly technique, combined with encircling ethylenediamine (EN) protectors to maintain the liquid crystal mesophase structure of TiO 2 primary particles, followed by calcination at higher temperature. The structures of the prepared mesoporous TiO 2 are characterized in detail by small‐angle and wide‐angle X‐ray diffraction, Raman spectra, N 2 adsorption/desorption isotherms, and transmission electron microscopy. Experimental results indicate that the well‐ordered mesoporous structure could be maintained up to 700 °C (M700) and also possesses large pore size (10 nm), high specific BET surface area (122 m 2 g −1 ), and high total pore volumes (0.20 cm 3 g −1 ), which is attributed to encircling EN protectors for maintaining the mesoporous framework against collapsing, inhibiting undesirable grain growth and phase transformation during the calcination process. A possible formation mechanism for the highly stable large‐pore mesoporous anatase TiO 2 is also proposed here, which could be further confirmed by TG/FT‐IR in site analysis and X‐ray photoelectron spectroscopy. The obtained mesoporous TiO 2 of M700 exhibit better photocatalytic activity than that of Degussa P25 TiO 2 for degradation of highly toxic 2,4‐dichlorophenol under UV irradiation. This enhancement is attributed to the well‐ordered large‐pore mesoporous structure, which facilitates mass transport, the large surface area offering more active sites, and high crystallinity that favors the separation of photogenerated electron‐hole pairs, confirmed by surface photovoltage spectra.