A Systematic Approach to Building Highly Porous, Noninterpenetrating Metal–Organic Frameworks with a Large Capacity for Adsorbing H 2  and CH 4 | Zendy

Lee Jeong Yong | Zendy; Pan Long | Zendy; Huang Xiaoying | Zendy; Emge Thomas J. | Zendy; Li Jing | Zendy

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A Systematic Approach to Building Highly Porous, Noninterpenetrating Metal–Organic Frameworks with a Large Capacity for Adsorbing H 2 and CH 4

Author(s) -

Lee Jeong Yong,

Pan Long,

Huang Xiaoying,

Emge Thomas J.,

Li Jing

Publication year - 2011

Publication title -

advanced functional materials

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 6.069

H-Index - 322

eISSN - 1616-3028

pISSN - 1616-301X

DOI - 10.1002/adfm.201001790

Subject(s) - materials science , porosity , metal organic framework , adsorption , methane , hydrogen , metal , chemical engineering , porous medium , inorganic chemistry , composite material , metallurgy , chemistry , organic chemistry , engineering

Highly porous metal organic framework materials having closely related structures and systematically tunable porosity demonstrate a high capacity for methane and hydrogen adsorption. At room temperature and ≈40 bars, the compounds Zn(BDC)(TED) 0.5 and Ni(NDC)(TED) 0.5 adsorb 242 cm 3 g −1 and 173 cm 3 g −1 of CH 4 , respectively. At 77 K, they take up 4.1 and 5.5 wt% of hydrogen at 40 and 65 bars, respectively.

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