High‐Performance Carbon‐LiMnPO 4 Nanocomposite Cathode for Lithium Batteries

A cathode material of an electrically conducting carbon‐LiMnPO 4 nanocomposite is synthesized by ultrasonic spray pyrolysis followed by ball milling. The effect of the carbon content on the physicochemical and electrochemical properties of this material is extensively studied. A LiMnPO 4 electrode with 30 wt% acetylene black (AB) carbon exhibits an excellent rate capability and good cycle life in cell tests at 55 and 25 °C. This electrode delivers a discharge capacity of 158 mAh g −1 at 1/20 C, 126 mAh g −1 at 1 C, and 107 mAh g −1 at 2 C rate, which are the highest capacities reported so far for this type of electrode. Transmission electron microscopy and Mn dissolution results confirm that the carbon particles surrounding the LiMnPO 4 protect the electrode from HF attack, and thus lead to a reduction of the Mn dissolution that usually occurs with this electrode. The improved electrochemical properties of the C‐LiMnPO 4 electrode are also verified by electrochemical impedance spectroscopy.