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Bioinspired Design of SrAl 2 O 4 :Eu 2+ Phosphor
Author(s) -
Kostova Mariya H.,
Zollfrank Cordt,
Batentschuk Miroslaw,
GoetzNeunhoeffer Friedlinde,
Winnacker Albrecht,
Greil Peter
Publication year - 2009
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.200800878
Subject(s) - phosphor , materials science , scanning electron microscope , luminescence , photoluminescence , rietveld refinement , monoclinic crystal system , powder diffraction , microstructure , energy dispersive x ray spectroscopy , spectroscopy , analytical chemistry (journal) , crystal structure , mineralogy , crystallography , composite material , optoelectronics , chemistry , chromatography , physics , quantum mechanics
A phosphor based on Sr 0.97 Al 2 O 4 :Eu 0.03 with a biomorphous morphology is manufactured via vacuum assisted infiltration of wood tissue ( Pinus sylvestris ) with a precursor nitrate solution. The nitrate solution penetrates homogeneously into the uniform arrangement of rectangular shaped tracheidal cells of the wood tissue. According to scanning electron microscopy, the original wood cell walls are completely transformed retaining the original wood structure. The major crystalline phase is monoclinic SrAl 2 O 4 , detected by X‐ray diffraction and confirmed by Rietveld refinement. Energy‐dispersive X‐ray analysis proves the homogeneous conversion of the original wood cell wall into Sr 0.97 Al 2 O 4 :Eu 0.03 struts. The optical properties of the resulting phosphor material are determined by photoluminescence and cathode‐luminescence spectroscopy in scanning electron microscopy. The biotemplated Sr 0.97 Al 2 O 4 :Eu 0.03 shows a characteristic green emission at 530 nm (2.34 eV). Shaping biomorphous SrAl 2 O 4 :Eu 2+ phosphor with a microstructure pseudomorphous to the bioorganic template anatomy offers a novel approach for designing micropatterned phosphor materials.