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Blue‐Emitting Cationic Iridium Complexes with 2‐(1 H ‐Pyrazol‐1‐yl)pyridine as the Ancillary Ligand for Efficient Light‐Emitting Electrochemical Cells
Author(s) -
He Lei,
Duan Lian,
Qiao Juan,
Wang Ruji,
Wei Peng,
Wang Liduo,
Qiu Yong
Publication year - 2008
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.200701505
Subject(s) - iridium , hexafluorophosphate , electroluminescence , pyridine , cationic polymerization , materials science , ionic liquid , tetrafluoroborate , electrochemistry , photochemistry , bipyridine , ligand (biochemistry) , chemistry , crystallography , medicinal chemistry , polymer chemistry , nanotechnology , crystal structure , organic chemistry , layer (electronics) , electrode , catalysis , biochemistry , receptor
Two blue‐emitting cationic iridium complexes with 2‐(1 H ‐pyrazol‐1‐yl)pyridine (pzpy) as the ancillary ligands, namely, [Ir(ppy) 2 (pzpy)]PF 6 and [Ir(dfppy) 2 (pzpy)]PF 6 (ppy is 2‐phenylpyridine, dfppy is 2‐(2,4‐difluorophenyl) pyridine, and PF 6 − is hexafluorophosphate), have been prepared, and their photophysical and electrochemical properties have been investigated. In CH 3 CN solutions, [Ir(ppy) 2 (pzpy)]PF 6 emits blue‐green light (475 nm), which is blue‐shifted by more than 100 nm with respect to the typical cationic iridium complex [Ir(ppy) 2 (dtb‐bpy)]PF 6 (dtb‐bpy is 4,4′‐di‐ tert‐ butyl‐2,2′‐bipyridine); [Ir(dfppy) 2 (pzpy)]PF 6 with fluorine‐substituted cyclometalated ligands shows further blue‐shifted light emission (451 nm). Quantum chemical calculations reveal that the emissions are mainly from the ligand‐centered 3 π – π * states of the cyclometalated ligands (ppy or dfppy). Light‐emitting electrochemical cells (LECs) based on [Ir(ppy) 2 (pzpy)]PF 6 gave green‐blue electroluminescence (486 nm) and had a relatively high efficiency of 4.3 cd A −1 when an ionic liquid 1‐butyl‐3‐methylimidazolium hexafluorophosphate was added into the light‐emitting layer. LECs based on [Ir(dfppy) 2 (pzpy)]PF 6 gave blue electroluminescence (460 nm) with CIE (Commission Internationale de L'Eclairage) coordinates of (0.20, 0.28), which is the bluest light emission for iTMCs‐based LECs reported so far. Our work suggests that using diimine ancillary ligands involving electron‐donating nitrogen atoms (like pzpy) is an efficient strategy to turn the light emission of cationic iridium complexes to the blue region.