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TiO 2 Nanoparticle–Photopolymer Composites for Volume Holographic Recording
Author(s) -
Sánchez C.,
Escuti M. J.,
van Heesch C.,
Bastiaansen C. W. M.,
Broer D. J.,
Loos J.,
Nussbaumer R.
Publication year - 2005
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.200500095
Subject(s) - materials science , photopolymer , nanoparticle , acrylate , holography , refractive index , monomer , diffraction efficiency , holographic data storage , chemical engineering , high refractive index polymer , titanium dioxide , composite material , optics , optoelectronics , polymer , grating , nanotechnology , physics , engineering
A new and efficient photopolymer for the recording of volume holograms is presented. The material comprises a mixture of UV‐sensitive acrylates and grafted titanium dioxide nanoparticles with an average size of 4 nm. We report the formation of holographic gratings with refractive‐index modulation amplitudes of up to 15.5 × 10 –3 —an improvement of more than a factor of four over the base material without nanoparticles—while maintaining a low level of scattering and a high transparency in the visible‐wavelength range. The influence of the composition of the acrylate system on the final properties of the holographic material is also investigated and discussed. The presence of multifunctional monomers favors the compositional segregation of the different components, while the addition of monofunctional acrylate, highly compatible with the grafting of the nanoparticles, favors the dilution of these nanoparticles.