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Generation of Compositional‐Gradient Structures in Biodegradable, Immiscible, Polymer Blends by Intermolecular Hydrogen‐Bonding Interactions
Author(s) -
Hexig B.,
Alata H.,
Asakawa N.,
Inoue Y.
Publication year - 2005
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.200400550
Subject(s) - miscibility , materials science , polymer , differential scanning calorimetry , polymer blend , chemical engineering , ethylene oxide , hydrogen bond , polymer chemistry , fourier transform infrared spectroscopy , composite material , copolymer , molecule , thermodynamics , organic chemistry , chemistry , physics , engineering
A biodegradable, immiscible poly(butylenes adipate‐ co ‐butylenes terephthalate) [P(BA‐ co ‐BT)]/poly(ethylene oxide) (PEO) polymer blend film with compositional gradient in the film‐thickness direction has been successfully prepared in the presence of a low‐molecular‐weight compound 4,4′‐thiodiphenal (TDP), which is used as a miscibility‐enhancing agent. The miscibilities of the P(BA‐ co ‐BT)/PEO/TDP ternary blend films and the P(BA‐ co ‐BT)/PEO/TDP gradient film were investigated by differential scanning calorimetry (DSC). The compositional gradient structure of the P(BA‐ co ‐BT)/PEO/TDP (46/46/8 w/w/w) film has been confirmed by microscopic mapping measurement of Fourier‐transform infrared spectra and dynamic mechanical thermal analysis. We have developed a new strategy for generating gradient‐phase structures in immiscible polymer‐blend systems by homogenization, i.e., adding a third agent that can enhance the miscibility of the two immiscible polymers through simultaneous formation of hydrogen bonds with two component polymers.