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Infiltrating Semiconducting Polymers into Self‐Assembled Mesoporous Titania Films for Photovoltaic Applications
Author(s) -
Coakley K.M.,
Liu Y.,
McGehee M.D.,
Frindell K.L.,
Stucky G.D.
Publication year - 2003
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.200304361
Subject(s) - materials science , semiconductor , mesoporous material , polymer , photovoltaic system , copolymer , exciton , nanotechnology , chemical engineering , organic semiconductor , optoelectronics , composite material , organic chemistry , condensed matter physics , ecology , chemistry , physics , engineering , biology , catalysis
Interpenetrating networks of organic and inorganic semiconductors are attractive for photovoltaic cells because electron transfer between the two semiconductors splits excitons. In this paper we show that films of titania with a uniform distribution of pore sizes can be made using a block copolymer as a structure‐directing agent, and that 33 % of the total volume of the film can be filled with a semiconducting polymer.

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