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Nanocomposite Electrolytes with Fumed Silica and Hectorite Clay Networks: Passive versus Active Fillers
Author(s) -
Walls H.J.,
Riley M.W.,
Singhal R.R.,
Spontak R.J.,
Fedkiw P.S.,
Khan S.A.
Publication year - 2003
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.200304333
Subject(s) - hectorite , fumed silica , materials science , electrolyte , nanocomposite , lithium (medication) , chemical engineering , ionic conductivity , rheology , ionic bonding , composite material , ion , organic chemistry , montmorillonite , chemistry , electrode , medicine , engineering , endocrinology
The use of nanocomposites constitutes a versatile and robust approach in the development of novel electrolytes with tailored electrochemical and mechanical characteristics. In this study, we examine the morphology, rheology, and ion‐transport properties of two types of nanocomposite electrolyte gels, one consisting of branched silica nanoparticles and the other composed of hectorite clay. In the first system with hydrophobic (fumed) silica, oligomers of poly(ethylene oxide) (PEO), and lithium salt, the silica acts as a passive filler and does not participate in ion transport. The electrochemical properties are controlled by the salt–PEO electrolyte, allowing for ionic conductivities greater than 10 –3 S cm –1 at ambient temperature. At sufficiently high concentrations, the silica forms an elastic gel possessing a large open network structure that provides for unimpeded ion mobility. In the second system composed of lithium‐exchanged hectorite filler, the nanoscale platelets serve as the anion. This active filler yields ionic conductivities in excess of 10 –4 S cm –1 and lithium transference numbers approaching unity. Similar to fumed silica, the hectorite clay also forms an elastic gel network. However, the morphologies of the two systems are distinctively different both in terms of network structure and characteristic length scale. These morphological differences manifest themselves in different rheological responses with regard to gel modulus and yield stress.