Premium
Hierarchical‐Porous Ceramic Foams by a Combination of Replica and Freeze Technique
Author(s) -
Schelm Katja,
Fey Tobias,
Dammler Kathleen,
Betke Ulf,
Scheffler Michael
Publication year - 2019
Publication title -
advanced engineering materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.938
H-Index - 114
eISSN - 1527-2648
pISSN - 1438-1656
DOI - 10.1002/adem.201801362
Subject(s) - materials science , porosity , slurry , sublimation (psychology) , sintering , composite material , ceramic , freeze drying , ceramic foam , template , compressive strength , porous medium , nanotechnology , psychology , psychotherapist , physics , thermodynamics
Open‐porous alumina foams with additional strut porosity are fabricated by a two‐step sponge‐replication based manufacturing process. As the first step, open cellular ceramic foams are prepared following the Schwarzwalder sponge replication technique. Therefore, organic foam templates are coated with different aqueous alumina slurries with a solid load between 20 and 40 vol% In a second step, an additional porosity is generated inside the foam struts by freezing of the foams at temperatures between −196 and −20 °C and subsequent sublimation drying. The hierarchical structure of both, cell pores and strut pores in the freeze‐dried material remains intact after drying, template removal, and sintering. Size, connectivity, and morphology of the strut pores strongly depend on the solid load of the alumina slurry and on the freezing temperature. Cellular structures with a strut porosity between 50% and 60% and a total porosity exceeding 90% are prepared, which show a compressive strength in between 0.4 to 0.6 MPa. Due to the additional strut porosity, the specific surface area of freeze‐dried replica foams increases from 70 cm 2 g −1 for conventionally prepared foams to 200 cm 2 g −1 for freeze‐dried foams, respectively.