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Influence of Ti‐Based Fillers on the Thermal Decomposition and Phase Development of Polysiloxane Derived Materials
Author(s) -
Hönack F.,
Riedel R.
Publication year - 2003
Publication title -
advanced engineering materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.938
H-Index - 114
eISSN - 1527-2648
pISSN - 1438-1656
DOI - 10.1002/adem.200390018
Subject(s) - materials science , thermal decomposition , filler (materials) , phase (matter) , titanium carbide , titanium , carbide , decomposition , composite material , thermal , chemical engineering , metallurgy , organic chemistry , meteorology , chemistry , physics , engineering
The addition of carbide‐forming filler particles like titanium or TiH 2 is a suitable way to adjust the thermal decomposition behavior and the phase development of polysiloxane precursors. Besides TiC as the main crystalline phase formed at 1100°C, titanium silicides are found, but no oxygen‐containing crystalline phases. Thermal simultaneous analysis shows that the reaction of filler particles and matrix starts approximately at 300°C.