Premium
Multiple mechanisms generate a universal scaling with dissipation for the air‐water gas transfer velocity
Author(s) -
Katul Gabriel,
Liu Heping
Publication year - 2017
Publication title -
geophysical research letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.007
H-Index - 273
eISSN - 1944-8007
pISSN - 0094-8276
DOI - 10.1002/2016gl072256
Subject(s) - scaling , turbulence , dissipation , microscale chemistry , mechanics , scalar (mathematics) , momentum transfer , physics , statistical physics , taylor microscale , kinetic energy , turbulence kinetic energy , turbulence modeling , work (physics) , range (aeronautics) , classical mechanics , thermodynamics , materials science , geometry , mathematics , optics , mathematics education , scattering , composite material
A large corpus of field and laboratory experiments support the finding that the water side transfer velocity k L of sparingly soluble gases near air‐water interfaces scales as k L ∼( ν ε ) 1/4 , where ν is the kinematic water viscosity and ε is the mean turbulent kinetic energy dissipation rate. Originally predicted from surface renewal theory, this scaling appears to hold for marine and coastal systems and across many environmental conditions. It is shown that multiple approaches to representing the effects of turbulence on k L lead to this expression when the Kolmogorov microscale is assumed to be the most efficient transporting eddy near the interface. The approaches considered range from simplified surface renewal schemes with distinct models for renewal durations, scaling and dimensional considerations, and a new structure function approach derived using analogies between scalar and momentum transfer. The work offers a new perspective as to why the aforementioned 1/4 scaling is robust.