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Riverine dissolved lithium isotopic signatures in low‐relief central Africa and their link to weathering regimes
Author(s) -
Henchiri Soufian,
Gaillardet Jérôme,
Dellinger Mathieu,
Bouchez Julien,
Spencer Robert G. M.
Publication year - 2016
Publication title -
geophysical research letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.007
H-Index - 273
eISSN - 1944-8007
pISSN - 0094-8276
DOI - 10.1002/2016gl067711
Subject(s) - weathering , geology , bedrock , geochemistry , sedimentary rock , continental crust , transect , earth science , geomorphology , crust , oceanography
The isotopic composition of dissolved lithium (δ 7 Li) near the Congo River mouth varied from 14‰ to 22‰ in 2010 and was negatively correlated to discharge. From the relationship between dissolved δ 7 Li and strontium isotopes, we suggest that this large variation is due to mixing of waters from two contrasting continental weathering regimes. One end‐member (high δ 7 Li ≈ 25‰) represents waters sourced from active lateritic soils covering the periphery of the basin (Li highly sequestered into secondary mineral products) and another representing blackwater rivers (low δ 7 Li ≈ 5.7‰) derived from the swampy central depression where high organic matter content in water leads to congruent dissolution of the Tertiary sedimentary bedrock. This suggests that the lithium isotopic signature of tropical low‐relief surfaces is not unique and traces the long‐term, large‐scale vertical motions of the continental crust that control geomorphological settings. This evolution should be recorded in the oceanic secular δ 7 Li curve.