Short organic carbon turnover time and narrow 14 C age spectra in early Holocene wetland paleosols

Paleosols contain information about the rates of soil organic carbon turnover when the soil was actively forming. However, this temporal information is often difficult to interpret without tight stratigraphic control on the age of the paleosol. Here we apply ramped pyrolysis/oxidation (Ramped PyrOx) 14 C analyses to evaluate age spectra of transgressive early Holocene paleosols from the Mississippi Delta in southeastern Louisiana, USA. We find 14 C age spectra from soil organic matter (SOM) in both paleosols and overlying basal peats that represent variability in age that is close to, or only slightly greater than, analytical uncertainty of 14 C measurements, despite different sources of carbon with likely disparate ages. Such age spectra have not previously been observed in the sedimentary record. Here they indicate vigorous soil carbon turnover prior to burial, which homogenized 14 C ages within SOM across the entire thermochemical spectrum. The weighted bulk 14 C ages from Ramped PyrOx of paleosols and overlying peats are identical within analytical and process‐associated uncertainty, and corroborate 14 C ages from charcoal fragments and plant macrofossils from the overlying peat. The youngest ages from Ramped PyrOx age spectra may also potentially be applied as chronometers for stratigraphic burial ages. Our results suggest rapid turnover (≪300 years) of carbon in these soils relative to input of allochthonous carbon, indicating that the 14 C age of different soil components is decoupled from thermochemical stability and instead reflects vigorous turnover processes. The concurrence of paleosol and peat 14 C ages also suggests that pedogenic processes were linked with the development of coastal marshes, and that the priming effect potentially masked the signal of allochthonous carbon inputs during sea level rise.