Open AccessInfluence of temperature, pressure, and oxygen fugacity on the electrical conductivity of dry eclogite, and geophysical implications
Author(s) -
Dai Lidong,
Hu Haiying,
Li Heping,
Wu Lei,
Hui Keshi,
Jiang Jianjun,
Sun Wenqing
Publication year - 2016
Publication title -
geochemistry, geophysics, geosystems
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.928
H-Index - 136
ISSN - 1525-2027
DOI - 10.1002/2016gc006282
Subject(s) - eclogite , mineral redox buffer , electrical resistivity and conductivity , activation energy , mineralogy , geology , analytical chemistry (journal) , polaron , oxygen , arrhenius equation , materials science , chemistry , geophysics , mantle (geology) , environmental chemistry , paleontology , physics , electrical engineering , engineering , organic chemistry , quantum mechanics , subduction , tectonics , electron
Abstract The electrical conductivity of eclogite was measured at temperatures of 873–1173 K and pressures of 1.0–3.0 GPa within a frequency range of 0.1–10 6 Hz using a YJ‐3000t multianvil press and Solartron‐1260 impedance/gain‐phase analyzer. Three solid‐state oxygen buffers (Cu + CuO, Ni + NiO, and Mo + MoO 2 ) were employed to control the oxygen fugacity. Experimental results indicate that the electrical conductivity of the samples tended to increase with increasing temperature, conforming to an Arrhenius relation. Under the control of a Cu + CuO oxygen buffer, the electrical conductivity of the eclogite decreased with a rise in pressure, and its corresponding activation volume and activation energy at atmospheric pressure were calculated as −2.51 ± 0.29 cm 3 /mole and 0.86 ± 0.12 eV, respectively. At 2.0 GPa, the electrical conductivity of the eclogite increased with increasing oxygen fugacity, and the preexponential factor increased while the activation enthalpy decreased. The observed positive exponential factor for the dependence of electrical conductivity on oxygen fugacity, as well as the negative activation volume, confirm that the hopping of small polarons is the dominant conduction mechanism in eclogite at high temperatures and pressures. Our results suggest that the electrical conductivity of dry eclogite under various redox conditions cannot explain the high anomalies in conductivity under stable midlower continental crust and under the Dabie‐Sulu ultrahigh‐pressure metamorphic belt of eastern China.