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Thorium distributions in high‐ and low‐dust regions and the significance for iron supply
Author(s) -
Hayes Christopher T.,
Rosen Jeffrey,
McGee David,
Boyle Edward A.
Publication year - 2017
Publication title -
global biogeochemical cycles
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.512
H-Index - 187
eISSN - 1944-9224
pISSN - 0886-6236
DOI - 10.1002/2016gb005511
Subject(s) - seawater , deposition (geology) , geotraces , thorium , environmental science , mineral dust , isotopes of thorium , plume , uranium , environmental chemistry , oceanography , aerosol , geology , chemistry , sediment , geography , paleontology , organic chemistry , meteorology , materials science , metallurgy
Abstract Thorium and uranium isotopes ( 232 Th, 230 Th, 238 U, and 234 U) were investigated to refine their use for estimating mineral dust deposition and Fe delivery to the ocean. U concentrations and isotope ratios were consistent with conservative behavior and can safely be described using published U‐salinity relationships and global average seawater isotopic composition. Near Barbados, waters affected by the Amazon outflow contained elevated 232 Th. This signals one region where the thorium‐dust method is inaccurate because of a confounding continental input. Dissolved 232 Th fluxes in this region suggest that Amazonian Fe supply to the adjacent open ocean is much larger than local atmospheric deposition. The colloidal content of dissolved Th south of Bermuda was found to be quite small (2–6%), similar to that found north of Hawaii, despite the order of magnitude higher dust deposition in the Atlantic. This finding supports the assumption that dissolved 232 Th and 230 Th are scavenged at the same rate despite their different sources and also sheds light on the increase of dissolved 232 Th fluxes with integrated depth. Outside the region influenced by Amazon River waters, dissolved 232 Th fluxes are compared with Bermudan aerosol Fe deposition to estimate that fractional Th solubility is around 20% in this region. Finally, new dissolved and soluble Fe, Mn, and Cr data from the subtropical North Pacific support the idea that Fe concentrations in the remote ocean are highly buffered, whereas 232 Th has a larger dynamic range between high‐ and low‐dust regions.