Open Access
Carbon and oxygen isotopes of bulk carbonate in sediment deposited beneath the eastern equatorial Pacific over the last 8 million years
Author(s) -
Reghellin Daniele,
Coxall Helen K.,
Dickens Gerald R.,
Backman Jan
Publication year - 2015
Publication title -
paleoceanography
Language(s) - English
Resource type - Journals
eISSN - 1944-9186
pISSN - 0883-8305
DOI - 10.1002/2015pa002825
Subject(s) - carbonate , geology , foraminifera , equator , oceanography , isotopes of oxygen , deep sea , calcite , isotopes of carbon , sediment , upwelling , geochemistry , total organic carbon , δ18o , mineralogy , stable isotope ratio , paleontology , benthic zone , environmental chemistry , latitude , chemistry , physics , organic chemistry , geodesy , quantum mechanics
Abstract To improve the understanding and utility of bulk carbonate stable carbon and oxygen isotope measurements, we examine sediment from cores in the eastern equatorial Pacific that span the last 8 Ma. We measured δ 13 C and δ 18 O in 791 samples from Integrated Ocean Drilling Program Site U1338 and Deep Sea Drilling Project Site 573, both located close to the Pacific equator. In 100 samples, we measured δ 13 C and δ 18 O on isolated <63 µm and <38 µm fractions, which concentrates calcareous nannofossil carbonate and progressively excludes foraminiferal carbonate. Bulk carbonate δ 13 C and δ 18 O records are similar to published records from other sites drilled near the equator and seem to reflect mixed layer conditions, albeit with some important caveats involving the precipitation of calcite by coccolithophores. The comparatively lower δ 13 C and δ 18 O of the <63 µm and <38 µm fractions in sediments younger than 4.4 Ma is attributed to an increase in deep‐dwelling planktic foraminifera material in bulk carbonate, shifting the bulk isotopic signals toward higher values. Bulk carbonate δ 13 C is similar over 2500 km along the Pacific equator, suggesting covarying concentrations and δ 13 C of dissolved inorganic carbon within surface waters since 8 Ma. Greater bulk sediment δ 13 C and δ 18 O, higher sedimentation rates, and low content of coarse material suggest intensified wind‐driven upwelling and enhanced primary productivity along the Pacific equator between 8.0 and 4.4 Ma, although a full understanding of bulk carbonate records will require extensive future work.