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Upper D region chemical kinetic modeling of LORE relaxation times
Author(s) -
GordilloVázquez F. J.,
Luque A.,
Haldoupis C.
Publication year - 2016
Publication title -
journal of geophysical research: space physics
Language(s) - English
Resource type - Journals
eISSN - 2169-9402
pISSN - 2169-9380
DOI - 10.1002/2015ja021408
Subject(s) - electron density , kinetic energy , dissociative recombination , electron , ionization , atomic physics , ionosphere , ion , physics , relaxation (psychology) , lightning (connector) , computational physics , atmospheric sciences , chemistry , recombination , geophysics , thermodynamics , classical mechanics , quantum mechanics , social psychology , psychology , biochemistry , power (physics) , gene
The recovery times of upper D region electron density elevations, caused by lightning‐induced electromagnetic pulses (EMP), are modeled. The work was motivated from the need to understand a recently identified narrowband VLF perturbation named LOREs, an acronym for LOng Recovery Early VLF events . LOREs associate with long‐living electron density perturbations in the upper D region ionosphere; they are generated by strong EMP radiated from large peak current intensities of ±CG (cloud to ground) lightning discharges, known also to be capable of producing elves. Relaxation model scenarios are considered first for a weak enhancement in electron density and then for a much stronger one caused by an intense lightning EMP acting as an impulsive ionization source. The full nonequilibrium kinetic modeling of the perturbed mesosphere in the 76 to 92 km range during LORE‐occurring conditions predicts that the electron density relaxation time is controlled by electron attachment at lower altitudes, whereas above 79 km attachment is balanced totally by associative electron detachment so that electron loss at these higher altitudes is controlled mainly by electron recombination with hydrated positive clusters H + (H 2 O) n and secondarily by dissociative recombination with NO + ions, a process which gradually dominates at altitudes >88 km. The calculated recovery times agree fairly well with LORE observations. In addition, a simplified (quasi‐analytic) model build for the key charged species and chemical reactions is applied, which arrives at similar results with those of the full kinetic model. Finally, the modeled recovery estimates for lower altitudes, that is <79 km, are in good agreement with the observed short recovery times of typical early VLF events, which are known to be associated with sprites.