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Diamine‐sulfuric acid reactions are a potent source of new particle formation
Author(s) -
Jen Coty N.,
Bachman Ryan,
Zhao Jun,
McMurry Peter H.,
Hanson David R.
Publication year - 2016
Publication title -
geophysical research letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.007
H-Index - 273
eISSN - 1944-8007
pISSN - 0094-8276
DOI - 10.1002/2015gl066958
Subject(s) - sulfuric acid , nucleation , particle (ecology) , aerosol , atmosphere (unit) , mixing (physics) , mixing ratio , chemistry , methanesulfonic acid , inorganic chemistry , materials science , meteorology , organic chemistry , physics , geology , oceanography , quantum mechanics
Atmospheric nucleation from sulfuric acid depends on the concentrations and the stabilizing effect of other trace gases, such as ammonia and amines. Diamines are an understudied class of atmospherically relevant compounds, and we examine how they affect sulfuric acid nucleation in both flow reactor experiments and the atmosphere. The number of particles produced from sulfuric acid and diamines in the flow reactor was equal to or greater than the number formed from monoamines, implying that diamines are more effective nucleating agents. Upper limits of diamine abundance were also monitored during three field campaigns: Lamont, OK (2013); Lewes, DE (2012); and Atlanta, GA (2009). Mixing ratios were measured as high as tens of parts per trillion by volume (GA and OK). Laboratory results suggest that diamines at these levels are important for atmospheric nucleation. Diamines likely participate in atmospheric nucleation and should be considered in nucleation measurements and models.