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Coupling atmospheric mercury isotope ratios and meteorology to identify sources of mercury impacting a coastal urban‐industrial region near Pensacola, Florida, USA
Author(s) -
Demers Jason D.,
Sherman Laura S.,
Blum Joel D.,
Marsik Frank J.,
Dvonch J. Timothy
Publication year - 2015
Publication title -
global biogeochemical cycles
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.512
H-Index - 187
eISSN - 1944-9224
pISSN - 0886-6236
DOI - 10.1002/2015gb005146
Subject(s) - mercury (programming language) , environmental science , mesoscale meteorology , atmospheric sciences , climatology , geology , computer science , programming language
Identifying the anthropogenic and natural sources of mercury (Hg) emissions contributing to atmospheric mercury on local, regional, and global scales continues to be a grand challenge. The relative importance of various direct anthropogenic emissions of mercury, in addition to natural geologic sources and reemission of previously released and deposited mercury, differs regionally and temporally. In this study, we used local‐scale, mesoscale, and synoptic‐scale meteorological analysis to couple the isotopic composition of ambient atmospheric mercury with potential sources of mercury contributing to a coastal urban‐industrial setting near a coal‐fired power plant in Pensacola, Florida, USA. We were able to broadly discern four influences on the isotopic composition of ambient atmospheric mercury impacting this coastal urban‐industrial region: (1) local to regional urban‐industrial anthropogenic emissions (mean δ 202 Hg = 0.44 ± 0.05‰, 1SD, n = 3), (2) marine‐influenced sources derived from the Gulf of Mexico (mean δ 202 Hg = 0.77 ± 0.15‰, 1SD, n = 4), (3) continental sources associated with north‐northwesterly flows from within the planetary boundary layer (mean δ 202 Hg = 0.65 ± 0.04‰, 1SD, n = 3), and (4) continental sources associated with north‐northeasterly flows at higher altitudes (i.e., 2000 m above ground level; mean δ 202 Hg = 1.10 ± 0.21‰, 1SD, n = 8). Overall, these data, in conjunction with previous studies, suggest that the background global atmospheric mercury pool is characterized by moderately positive δ 202 Hg values; that urban‐industrial emissions drive the isotopic composition of ambient atmospheric mercury toward lower δ 202 Hg values; and that air‐surface exchange dynamics across vegetation and soils of terrestrial ecosystems drive the isotopic composition of ambient atmospheric mercury toward higher positive δ 202 Hg values. The data further suggest that mass‐independent fractionation (MIF) of both even‐mass‐ and odd‐mass‐number isotopes, likely generated by photochemical reactions in the atmosphere or during reemission from terrestrial and aquatic ecosystems, can be obscured by mixing with anthropogenic emissions having different MIF signatures.