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Surface and free tropospheric sources of methanesulfonic acid over the tropical Pacific Ocean
Author(s) -
Zhang Yuzhong,
Wang Yuhang,
Gray Burton Alonza,
Gu Dasa,
Mauldin Lee,
Cantrell Christopher,
Bandy Alan
Publication year - 2014
Publication title -
geophysical research letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.007
H-Index - 273
eISSN - 1944-8007
pISSN - 0094-8276
DOI - 10.1002/2014gl060934
Subject(s) - methanesulfonic acid , troposphere , aerosol , dimethyl sulfide , sulfate , atmospheric sciences , sulfur , environmental science , sulfur cycle , climatology , environmental chemistry , chemistry , geology , organic chemistry
The production of sulfate aerosols through sulfur chemistry in marine environments is critical to the tropical climate system. However, not all sulfur compounds have been studied in detail. One such compound is methanesulfonic acid (MSA). In this study, we use a one‐dimensional chemical transport model to analyze the observed vertical profiles of gas phase MSA during the Pacific Atmospheric Sulfur Experiment. The observed sharp decrease in MSA from the surface to 600 m implies a surface source of 4.0 × 10 7 molecules/cm 2 /s. Evidence suggests that this source is photolytically enhanced in daytime. We also find that the observed large increase of MSA from the boundary layer into the lower free troposphere (1000–2000 m) results mainly from the degassing of MSA from dehydrated aerosols. We estimate a source of 1.2 × 10 7 molecules/cm 2 /s to the free troposphere through this pathway. This source of soluble MSA could potentially provide an important precursor for new particle formation in the free troposphere over the tropics, affecting the climate system through aerosol‐cloud interactions.